6%氟环唑 7.6%吡唑醚菌酯SE配方及MSDS（巴斯夫公司）.docx

6%氟环理+7.6%毗理醮菌酯SE配方及MSDS（巴斯夫公司）SafetydatasheetPage:1/13BASFSafetydatasheetaccordingtoRegulation(EC)No.1907/2006Date/Revised:23.12.2011Version:1.0Product:1.UMEN(IDno.30115318SDSCPAIEEN)Dateofprint23.12.20111.Identificationofthesubstance/mixtureandoftheCOmPany/undertakingProductidentifier1.UMENRelevantidentifiedusesofthesubstanceormixtureandusesadvisedagainstRelevantidentifieduses:cropprotectionproduct,fungicideDetailsofthespplierofthesafetydatasheetCompany:BASFSE670561.udwigshafenGERMANYContactaddress:BASEplcPOBox4,EarlRoad,CheadleHulme,Cheadle,CheshireSK86QG,UNITEDKINGDOMTelephone:+44161485-6222E-mailaddress:product-safety-11orthbasfEmergencytelephonenumberInternationalemergencynumber:Telephone:+491802273-1122.HazardsIdentification1.abelelementsAccordingtoDirective67/548/EECor1999/45/ECClassificationZlabellinginaccordancewithIrishregulations.Hazardsymbol(三)XnHarmful.Page:2/13BASFSafetydatasheetaccordingtoRegulation(EC)No.1907/2006Date/Revised:23.12.2011Version:1.0Product:1.UMEN(IDno.30415318/SDS_CPA_IE/EN)Dateofprint23.12.2011NDangerousfortheenvironment.R-phrase(三)R2022Harmfulbyinhalationandifswallowed.R38Irritatingtoskin.R401.imitedevidenceofacarcinogeniceffect.Rl3Maycausesensitizationbyskincontact.R5053Verytoxictoaquaticorganisms,maycauselong-termadverseeffectsintheaquaticenvironmcnt.R62Possibleriskofimpairedferti1ily.R63Possibleriskofharmtotheunbornchild.S-phrase(三)S2Keepoutofthereachofchildren.S13Keepawayfromfood,drinkandanimalfeedingstuffs.S2021Whenusingdonoteat,drinkorsmoke.S24Avoidcontactwithskin.S35Thismaterialanditscontainermustbedisposedofinasafeway.S3637Wearsuitableprotectiveclothingandgloves.S46Ifswallowed,seekmedicaladviceimmediatelyandshowthiscontainerorlabel.S57Useappropriatecontainertoavoidenvironmentalcontamination.Hazarddeterminingcomponent(三)forlabelling:PYRAC1.oSTROBN,EPOXlCONAZO1.E,SO1.VENTNAPHTHAClassificationofthesubstanceormixtureAccordingtoDirective67/548/EECor1999/45/ECCare.Cat.3RE3(asinAnnexIofDirective67/548/EEC)RF3PossibleHazards:Harmfulbyinhalationandifswallowed.Irritatingtoskin.1.imitedevidenceofacarcinogeniceffect.Maycausesensitizationbyskincontact.Verytoxictoaquaticorganisms,maycauselong-termadverseeffectsintheaquaticenvironment.Possibleriskofimpairedfertility.Possibleriskofharmtotheunbornchild.Fortheclassificationsnotwrittenoutinfullinthissectionthefulltextcanbefoundinsection16.OtherhazardsAccordingtoRegulation(EC)No1272/2008C1.PPage:3/13BASFSafetydatasheetaccordingtoRegulation(EC)No.1907/2006Date/Revised:23.12.2011Version:1.0Product:1.UMEN(IDno.30415318/SDS_CPA_IEEN)Dateofprint23.12.2011Seesection12-ResultsofPBTandVPVBassessment.Ifapplicableinformationisprovidedinthissectiononotherhazardswhichdonotresultinclassificationbutwhichmaycontributetotheoveral1hazardsofthesubstanceormixture.3.CompositionZInformationonIngredientsMixturesChemicalnaturecropprotectionproduct,fungicide,SUSPo-emuIsion(SE)HazardousingredientsaccordingtoDirective1999/45/ECPyraclostrobinContent(WW):7.6%CASNumber:175013-18-0Hazardsymbol(三):T,NR-phrase(三):23,38,50/53EpoxiconazoleContent(WW):6%CASNumber:133855-98-8EC-Number:406-850-2REACHregistrationnumber:01-0000015634-70INDEX-Number:613-175-00-9HazardSymbol(三):Xn,NR-phrase(三):40,62,63,51/53Care.Cat.3RE3RF3Solventnaphtha(petroleum),heavyarom.;Kerosine-unspecifiedContent(WW):=25%CASNumber:64742-94-5EC-Number:265-198-5INDEX-Number:649-424-00-3Hazardsymbol(三):Xn,NR-phrase(三):65,51/53fattyalcoholethoxylateContent(W/W):=10%CASNumber:68002960Hazardsymbol(三):T,NR-phrase(三):23,50phenolsulfonicacid-formaldehyde-po)ycondcnsateassodiumsaltContent(WW):=5%R-phrase(三):52/53Page:4/13BASFSafetydatasheetaccordingtoRegulation(EC)No.1907/2006Date/Revised:23.12.2011Version:1.0Product:1.UMEN(IDno.30415318/SDS_CPA_IE/EN)Dateofprint23.12.2011Propane-l,2-diolContent(WW):=2%CSNumber:57-55-6EC-Number:200-338-0REACHregistrationnumber:01-2119456809-23naphthaleneContent(WW):=0.2%CSNumber:91-20-3EC-Number:202-049-5INDEX-Number:601-052-00-2Hazardsymbol(三):Xn,NR-phrase(三):22,40,50/53Care.Cat.3Fortheclassificationsnotwrittenoutinful1inthissection,includingtheindicationofdanger,thehazardsymbols,theRphrases,andthehazardstatements,theful1textislistedinsection16.4.First-AidMeasuresDescriptionoffirstaidmeasuresRemovecontaminatedclothing.Ifinhaled:Keeppatientcalm,removetofreshair,seekmedicalattention.Onskincontact:Washthoroughlywithsoapandwater.Oncontactwitheyes:Washaffectedeyesforatleast15minutesunderrunningwaterwitheyelidsheldopen.Oningestion:Immediatelyrinsemouthandthendrink200-300mlofwater,seekmedicalattention.Mostimportantsymptomsandeffects,bothacuteanddelayedSymptoms:Themostimportantknownsymptomsandeffectsaredescribedinthelabelling(seesection2)and/orinsection11.,Furtherimportantsymptomsandeffectsaresofarnotknown.IndicationofanyimmediatemedicalattentionandspecialtreatmentneededTreatment:Treataccordingtosymptoms(decontamination,vitalfunctions),noknownspecificantidote.5.Fire-FightingMeasuresExtinguishingmediaSuitableextinguishingmedia:waterspray,carbondioxide,foam,drypowderSpecialhazardsarisingfromthesubstanceormixturePage:5/13BASESafetydatasheetaccordingtoRegulation(EC)No.1907/2006Date/Revised:23.12.2011Version:1.0Product:1.UMEN(IDno.30415318/SDS_CPA_IE/EN)Dateofprint23.12.2011carbonmonoxide,hydrogenchloride,hydrogenfluoride,nitrogenoxides,OrganochloriccompoundsTheSUbSIanCeS/groupsofsubstancesmentionedcanbereleasedincaseoffire.Adviceforfire-fightersSpecialprotectiveequipment:Wearself-containedbreathingapparatusandchemical-protectiveclothing.Furtherinformation:Incaseoffireand/orexplosiondonotbreathefumes.Keepcontainerscoolbysprayingwithwaterifexposedtofire.Collectcontaminatedextinguishingwaterseparately,donotallowtoreachsewageoreffluentsystems.Disposeoffiredebrisandcontaminatedextinguishingwaterinaccordancewithofficialregulations.6.AccidentalReleaseMeasuresPersonalprecautions,protectiveequipmentandemergencyproceduresUsepersonalprotectiveclothing.Avoidcontactwiththeskin,eyesandclothing.Donotbreathevapour/spray.EnvironmentalprecautionsDonotdischargeintothesubsoi1/soi1.Donotdischargeintodrains/surfaceWaterS/groundwater.Donotallowcontaminationofpublicdrainsorsurfaceorgroundwaters.InformlocalwaterplcifspillageentersdrainsandtheEnvironmentalProtectionAgencyifitenterssurfaceorgroundwaters.Keeppeopleandanimalsaway.MethodsandmaterialforcontainmentandcleaningupForsmallamounts:Pickupwithsuitableabsorbentmaterial(e.g.sand,sawdust,general-purposebinder,kieselguhr).Forlargeamounts:Dikespi1lagc.Pumpoffproduct.Disposeofabsorbedmaterialinaccordancewithregulations.ColIectwasteinsuitablecontainers,whichcanbelabeledandsealed.ReferencetoothersectionsInformationregardingexposurecontro1s/pcrsona1protectionanddisposalconsiderationscanbefoundinsection8and13.7.HandlingandStoragePrecautionsforsafehandlingNospecialmeasuresnecessaryifstoredandhandledcorrectly.Ensurethoroughventilationofstoresandworkareas.Whenusingdonoteat,drinkorsmoke.Handsand/orfaceshouldbewashedbeforebreaksandattheendoftheshift.Protectionagainstfireandexplosion:Vapoursmayformignitablemixturewithair.Preventelectrostaticcharge-sourcesofignitionshouldbekeptwellclear-fireextinguishersshouldbekepthandy.Conditionsforsafestorage,includinganyincompatibi1itiesSegregatefromfoodsandanimalfeeds.Furtherinformationonstorageconditions:Keepawayfromheat.Protectfromdirectsunlight.Storeprotectedagainstfreezing.Page:6/13BASFSafetydatasheetaccordingtoRegulation(EC)No.1907/2006Date/Revised:23.12.2011Version:1.0Product:1.UMEN(IDno.30415318/SDS_CPA_IE/EN)Dateofprint23.12.2011Protectfromtemperaturesbelow:0CTheproductcancrystallizebelowthelimittemperature.Protectfromtemperaturesabove:40CChangesinthepropertiesoftheproductmayoccurifsubstance/productisstoredaboveindicatedtemperatureforextendedperiodsoftime.Specificenduse(三)Fortherelevantidentifieduse(三)listedinSection1theadvicementionedinthissection7istobeobserved.8.ExposureContro1s/Pcrsona1ProtectionControlparametersComponentswithworkplacecontrolparameters57-55-6:Propane-1,2diolTWAvalue470mgm3;150ppm(0EI.(IE),TotalvapourandparticulatesTWvalue10mgm3(OE1.(IE),Particulate91-203:naphthaleneTWAvalue50mgm3;10ppm(OE1.(IE)STE1.value75mgm3;15ppm(OE1.(IE)RefertothecurrentscheduleofoccupationalexposurestandardspublishedbytheIrishHS.Fornorma1useandhandlingrefertotheproductlabel/leaflet.Inal1othercasesthefollowingapply.ExposurecontrolsPersonalprotectiveequipmentRespiratoryprotection:Respiratoryprotectionincaseofvapour/aerosolrelease.Wearrespiratoryprotectionifventilationisinadequate.Particlefilterwithmediumefficiencyforsolidand1iquidparticles(e.g.EN143or149,TypeP2OrFFP2)Handprotection:Suitablechemicaresistantsafetygloves(EN374)alsowithprolonged,directcontact(Recommended:Protectiveindex6,corresponding480minutesofpermeationtimeaccordingtoEN374):E.g.nitrilerubber(0.4mm),chloroprenerubber(0.5mm),butylrubber(0.7mm)andotherEyeprotection:Safetyglasseswithside-shields(framegoggles)(e.g.EN166)Bodyprotection:Bodyprotectionmustbechosendependingonactivityandpossibleexposure,e.g.apron,protectingboots,ChCnIiCal-ProteCliOnsuit(accordingtoEN14605incaseofsplashesorENISO13982incaseofdust).GeneralsafetyandhygienemeasuresThestatementsonpersonalprotectiveequipmentintheinstructionsforuseapplywhenhandlingcrop-protectionagentsinfinal-consumerpacking.Wearingofclosedworkclothingisrecommended.Storeworkclothingseparately.Keepawayfromfood,drinkandanimalfeedingstuffs.Page:7/13BASFSafetydatasheetaccordingtoRegulation(EC)No.1907/2006Date/Revised:23.12.2011Version:1.0Product:1.UMEN(IDno.30415318/SDS_CPA_IE/EN)Dateofprint23.12.20119.PhysicalandChemicalPropertiesInformationonbasicphysicalandchemicalpropertiesForm:liquid,suspensionColour:off-whiteOdour:faintlyaromaticOdourthreshold:notdeterminedpHvalue:approx.6.6(1%(m)Freezingpoint:-3.2Cboilingtemperature:approx.100CFlashpoint:Non-flammable.,Noflashpoint-Measurementmadeuptotheboilingpoint.(STMD93)Evaporationrate:notapplicableFlammability:nothighlyflammable1.owerexplosionlimit:notdeterminedUpperexplosionlimit:notdeterminedIgnitiontemperature:473C(Directive92/69/EEC,A.15)Informationon:solventnaphthaVapourpressure:0.003kPa(20C)0.025kPa(38C)0.028hPa(50C)Density:approx.1.05g/cm3(20C)Relativevapourdensity(air):notdeterminedSolubilityinwater:dispersibleThermaldecomposition:125C,110kj/kg(DSC(OECD113)160C,305kj/kg(DSC(OECD113)Viscosity,dynamic:52.7mPa.s(20C,100ls)Viscosity,kinematic:38.2mm2/s(40C)Explosionhazard:notexplosive(calculated)Firepromotingproperties:notfire-propagating(Directive2004/73/EC,A.21)OtherinformationOtherInformation:Ifnecessary,informationonotherphysicalandchemicalparametersisindicatedinthissection.Page:8/13BASFSafetydatasheetaccordingtoRegulation(EC)No.1907/2006Date/Revised:23.12.2011Version:1.0Product:1.UMEN(IDno.30415318/SDS_CPA_IE/EN)Dateofprint23.12.201110.Stabi1ityandReactivityReactivityNohazardousreactionsifstoredandhandledasprescribed/indicated.Chemicalstabi1ityTheproductisstableifstoredandhandledasprescribed/indicated.PossibilityofhazardousreactionsNohazardousreactionsifstoredandhandledasprescribed/indicatecl.ConditionstoavoidSeeMSDSsection7-Handlingandstorage.IncompatiblematerialsSubstancestoavoid:strongoxidizingagents,strongbases,strongacidsHazardousdecompositionproductsHazardousdecompositionproducts:Nohazardousdecompositionproductsifstoredandhandledasprescribed/indicated.11.ToxicologicalInformationInformationontoxicologicaleffectsAcutetoxicityExpcrimcntalZcalculateddata:1.D50rat(oral):300-500mg/kg(OECDGuideline423)1.C50rat(byinhalation):3.22mg/14hnaerosolwastested.1.D50rat(dermal):4,000mg/kgIrritationExperimentalZcalculateddata:Skincorrosion/irritationrabbit:Irritant.Seriouseyedamage/irritationrabbit:Slightlyirritating.Rcspiratory/SkinsensitizationExperimentalZcalculateddata:modifiedBuehlertestguineapig:Causedskinsensitizationinanimalstudies.Germcel1mutagenicityPage:9/13BASFSafetydatasheetaccordingtoRegulation(EC)No.1907/2006Date/Revised:23.12.2011Version:1.0Product:1.UMEN(IDno.30415318/SDS_CPA_JEEN)Dateofprint23.12.2011Assessmentofmutagenicity:Mutagenicitytestsrevealednogenotoxicpotential.Theproducthasnotbeentested.Thestatementhasbeenderivedfromthepropertiesoftheindividualcomponents.CarcinogcnicityAssessmentofcarcinogenicity:Theproducthasnotbeentested.Thestatementhasbeenderivedfromthepropertiesoftheindividua1components.1.imitedevidenceofacarcinogeniceffect.Informationon:EpoxiconazoleAssessmentofcarcinogenicity:1.imitedevidenceofacarcinogeniceffect.ReproductivetoxicityInformalionon:EpoxiconazoleAssessmentofreproductiontoxicity:Possibleriskofimpairedfertility.DevelopmentaltoxicityInformationon:EpoxiconazoleAssessmentofteratogenicity:Possibleriskofharmtotheunbornchild.RepeateddosetoxicityandSpecifictargetorgantoxicity(repeatedexposure)Informationon:EpoxiconazoleAssessmentofrepeateddosetoxicity:Repeatedexposuretolargequantitiesmayaffectcertainorgans.Informationon:PyraclostrobinAssessmentofrepeateddosetoxicity:Nosubstance-specificOrganotoxicitywasobservedafterrepeatedadministrationofhighdosestoanimals.OtherrelevanttoxicityinformationMisusecanbeharmfultohealth.Theproducthasnotbeentested.Thestatementhasbeenderivedfromproductsofasimilarstructureorcomposition.12.EcologicalInformationToxicityToxicitytofish:1.C50(96h)0.074mgl,OncorhynchusmykissNoobservedeffectconcentration(96h)0.036mgl,OncorhynchusmykissPage:10/13BASFSafetydatasheetaccordingtoRegulation(EC)No.1907/2006Date/Revised:23.12.2011Version:1.0Product:1.UMEN(IDno.30415318/SDS_CPA_IE/EN)Dateofprint23.12.2011Aquaticinvertebrates:EC50(48h)0.14mg/,DaphniamagnaAquaticplants:EC50(72h)5.05mg/1(growthrate),Pseudokirchnerie11asubcapitataPersistenceanddegradabilityInformationon:EpoxiconazoleAssessmentbiodegradationandelimination(H20):Notreadi1ybiodegradable(byOECDcriteria).Informationon:PyraclostrobinAssessmentbiodegradationandelimination(H20):NotreadiIybiodegradable(byOECDcriteria).BioaccumulativepotentialInformationon:EpoxiconazoleBioaccumulationpotential:Bioconcentrationfactor:59-70,Oncorhynchusmykiss(OECD-Guideline305)Doesnotaccumulateinorganisms.Informationon:PyraclostrobinBioaccuniulationpotential:Bioconcentrationfactor:379507,Oncorhynchusmykiss(OECD-Guideline305)Accumulationinorganismsisnottoheexpected.Mobilityinsoi1(andothercompartmentsifavai!able)Informationon:EpoxiconazoleAssessmenttransportbetweenenvironmentalcompartments:Followingexposuretosoil,adsorptiontosolidsoilparticlesisprobable,thereforecontaminationofgroundwaterisnotexpected.Informationon:PyraclostrobinAssessmenttransportbetweenenvironmentalcompartments:Followingexposuretosoil,adsorptiontosolidsoi1particlesisprobable,thereforecontaminationofgroundwaterisnotexpected.ResultsofPBTandrPvBassessmentTheproductdoesnotcontainasubstancefullfillingthePBT(persiste11tbiOaccumulative/toxic)criteriaorthevPvB(verypersistent/verybioaccumulative)criteria.AdditionalinformationOtherecotoxicologicaladvice:Donotdischargeproductintotheenvironmentwithoutcontrol.Theproducthasnotbeentested.Thestatementsonecotoxicologyhavebeenderivedfromproductsofasimilarstructureandcomposition.Page:11/13BASFSafe