60种农药的液相色谱、标准溶液定量离子色谱图.docx

《60种农药的液相色谱、标准溶液定量离子色谱图.docx》由会员分享，可在线阅读，更多相关《60种农药的液相色谱、标准溶液定量离子色谱图.docx（24页珍藏版）》请在课桌文档上搜索。

1、附录A（资料性）60种农药的化学信息、分析参数、检出限、定量限饲料中60种农药及其代谢物的化学信息、分析参数、检出限和定量限见表A.1表A.160种农药及代谢物的化学信息、分析参数、检出限、定量限序号中文名称英文名称CAS号纯度检出限定量限溶剂gkgg&g1阿维菌素abameciin71751-41-290%620甲醇2胺菊酯tetramethrin7696-12-090%0.65丙酮3毗虫咻imidacloprid105827-78-990%0.65甲醇4毗理雄菌酯Pyraclostrobin175013-18-090%0.35丙酮5丙环哇propiconazole60207-90-190%

2、1.815甲醇6丙溟磷profenofbs41198-08-790%1550丙酮7虫酰胧tebuIenozide112410-23-890%0.35甲醉8除虫服diflubenzuron35367-38-590%0.245甲醇9故百虫trichlorfon52-68-690%310丙酮IO敌草隆diuron330-54-190%0.65甲醇11敌敌畏dichlorvos62-73-790%1.510丙酮12皖虫眯ace(amiprid135410-20-790%0.35甲醇13咤酰菌胺boscalid188425-85-690%1.25甲醇14毒死婢Chlorpyrifos2921-88-29

3、0%1.25丙酮15对硫磷parathion56-38-290%310乙月青16多菌灵carbendazim10605-21-790%0.65乙脯17多杀霉素Spinosad131929-60-790%0.65甲醇18二苯胺diphenylamine122-39-490%1550甲醇19二嗪磷diazinon333-41-590%0.245环己烷20械胺鼠菊酯Iau-Fluvalinate102851-06-990%2.410丙酮21氟虫睛Fipronil120068-37-390%0.065乙腾氨虫睛碉fipronil-sulfbne120068-36-290%0.155丙酮械虫腊硫酸（亚飒

4、）fipronil-sulfide120067-83-690%0.065丙酮氟甲睛fipronil-desulfinyl205650-65-390%0.65丙酮22氟硅嘎Ausilazole85509-19-990%0.125乙储23甲拌磷phorate298-02-290%0.155乙睛甲拌磷飒phoratesulfone2588-04-790%510乙月青甲拌磷亚碗phoratesulfoxide2588-03-690%510乙脯24甲基硫菌灵thiophanate-methyl23564-05-890%2.45甲醇25甲基异柳磷isofenphos-methyl99675-03-390%

5、0.155丙酮26甲硫威methiocarb2032-65-790%0.65异丙醇甲硫威碉methiocarbsulfone2179-25-190%510异丙醉序号中文名称英文名称CAS号纯度检出限定量限溶剂gkgg&g甲硫威亚飒methiocarbsulfoxide2635-10-190%510异丙醉27甲蔡威carbaryl63-25-290%0.35甲醇28甲粗菊酯fenpropathrin64257-84-790%1.25乙腊29甲霜灵metalaxyl57837-19-190%0.125甲苯30久效磷monocrotophos6923-22-490%0.65甲醇31抗螃威pirimi

6、carb23103-98-290%0.125乙腊脱甲基抗螃威pirimicarb-desmethyl30614-22-390%510乙睛脱甲基甲酰胺基抗蝇威pirimicarb-desmethyl-formamido27218-04-890%510乙脯32克百威carbofuran1563-66-290%0.35甲醇3-羟基克百威3-hydroxycarbofuran16655-82-690%1.25乙酸乙酯33噎氧灵quinoxyfen124495-18-790%0.65甲醇34乐果dimethoate60-51-590%0.065丙酮35联苯菊酯bifenthrin82657-04-390

7、%1.25丙酮36氯毗嘴横隆halosulfuron-methyl100784-20-190%0.65乙脯37马拉硫磷malathion121-75-590%0.245乙腊马拉氧磷malaoxon1634-78-290%510乙睛38嘴菌酯azoxystrobin131860-33-890%0.155丙酮39灭多威methomyl16752-77-590%0.65丙酮40灭线磷ethoprophos131948-490%510甲醇41三环嘎tricyclazole41814-78-290%0.65乙脯42三哇醇triadimenol55219-65-390%4.85乙腊43三嚏酮Iriadim

8、efon43121-43-390%9.632甲醉44杀扑磷methidathion950-37-890%0.2410甲醇45水胺硫磷isocarbophos24353-61-590%1550乙脂46萎锈灵carboxin5234-68-490%0.245甲醉47戊哇醇tebuconazol804434-090%0.245乙储48烯畦醇diniconazol76714-88-090%1.25甲醇49辛硫磷phoxim14816-18-390%1.25甲呼50亚胺硫磷phosmet732-11-690%0.155乙脯氧亚胺硫磷phosmetoxon3735-33-990%510乙腊51氧化萎锈灵o

9、xycarboxin5259-88-190%0.125乙脂52乙拌磷disulfbton298-04-490%1.25甲醇内吸磷-S-碉demeton-S-sulfbne2496-91-590%510甲醇内吸磷-S-亚飒(Iemeton-S-Sulfoxide2496-92-690%510甲醇乙拌磷碉disulfbtonsulfone2497-06-590%510甲醇序号中文名称英文名称CAS号纯度检出限定量限溶剂gkgg&g乙拌磷亚硼disulfbtonsulfoxide2497-07-690%510甲醉53异嗯哇草酮isoxaflutole141112-29-090%0.65乙脯异嗯嗖草酮

10、-二酮脂IsoxaflutoIe-Ciiketonitrile143701-75-190%510乙腊54乙硫磷eihion563-12-290%510甲醇55乙霉威diethofencarb87130-20-990%0.125甲醇56乙哝硫磷etrimfbs38260-54-790%510甲醇57异丙威isoprocarb2631-40-590%0.65甲醇58抑霉一imazalil35554-44-090%1.55甲醇59苛虫威indoxacarb144171-61-990%0.65甲醇60仲丁灵butralin33629-47-990%0.35丙酮附录B(资料性)60种农药的液相色谱串联质

11、谱分析参数饲料中60种农药及其代谢物的液相色谱一串联质谱分析参数见表B.1表B.160种农药及代谢物的60种农药的液相色谱一串联质谱分析参数序号保留时间中文名称英文名称离子类型QlQ3去簇电压(V)碰撞能量(eV)116.72阿维菌素abamectin定量离子890.5305.18()45定性离子890.5567.18020214.06胺菊酯tetramethrin定量离子332.2164.15539定性离子332.2135.1553932.99毗虫咻imidacloprid定量离子256.1209.16031定性离子238181551445.67叱哩雄菌酯Pyraclostrobin定量离子

12、3881635035定性离子3881945017510.46丙环喋propiconazole定量离子3421598045定性离子342698047613.13丙滨磷profenofbs定量离子3733037027定性离子3733457()1875.53虫酰胧Cebufenozide定量离子3531334532定性离子35329745128939除虫服diflubenzuron定量离子3111585520定性离子311141554892.67敌百虫trichlorfon定量离子2572216015定性离子2571096030106.13敌草隆diuron定量离子233.1726049定性离子23

13、3.1160.16039Il4.65敌敌畏dichlorvos定量离子2211096524定性离子2211456519123.07喔虫眯acetamiprid定量离子2231267031定性离子223567()45139.01咤酰菌胺boscalid定量离子343.2307.26032定性离子343.227160451414.77毒死婢Chlorpyrifbs定量离子3501985530定性离子350795565154.39对硫磷parathion定量离子2922365519定性离子2922645513162.33多菌灵carbendazim定量离子192.1160.17026定性离子192.

14、1132.17048177.66多杀霉素spinosad定量离子732.514212049定性离子732.598120100序号保留时间中文名称英文名称离子类型QlQ3去簇电压(V)碰撞能量(eV)189.98二苯胺diphenylamine定量离子170936534定性离子1701537327198.32二嗪磷diazinon定量离子305169.17631定性离子305153.276312017.11氟胺氯菊酯tau-Fluvalinate定量离子503.2181.27050定性离子503.2208.17()152110.84氟虫脂Fipronil定量离子434.9329.8-60-23定

15、性离子434.9249.8-60-4011.98氨虫脯碉Hpronil-Sulfone定量离子450.9282-70-35定性离子450.9415-70-2312.04氟虫脂硫酸(亚飒)fipronil-sulfide定量离子419383.1-70-16定性离子419262.1-70-35定性离子419314-70-2711.30氟甲睛fipronil-desulfinyl定量离子387.1351.1-55-15定性离子387.1282.1-55-42229.39氟硅畦Ausikizole定量离子3162478026定性离子31616580482312.56甲拌磷phorale定量离子2617

16、54013定性离子26119940107.52甲拌磷碉phoratesulfone定量离子293.097.06550定性离子293.0115.065355.53甲拌磷亚飒phoratesulfoxide定量离子277.0199.02513定性离子277.0153.02519244.46甲基硫菌灵lhiophanaie-methy1定量离子343.1151.16042定性离子343.1311.160162512.00甲基异柳磷isofenphos-methyl定量离子332.1230.93015定性离子332.11213050267.90甲硫威methioccirb定量离子226.2121.15

17、029定性离子226.2169.150133.30甲硫威碉methiocarbsulfone定量离子258.1201.15013定性离子258.1122.150202.53甲硫威亚飒methiocarbsulfoxide定量离子242.1185.13718定性离子242.1122.13738275.66甲蔡威carbaryl定量离子202.1145.15012定性离子202.11127.150492814.77甲毓菊酯fenpropathrin定量离子3501256037定性离子350976049296.17甲霜灵metalaxyl定量离子280.1192.26023定性离子280.1220.

18、26018序号保留时间中文名称英文名称离子类型QlQ3去簇电压(V)碰撞能量(eV)302.27久效磷Inonocrotophos定量离子2241935012定性离子2241275018314.60抗斯威pirimicarb定量离子239726049定性离子23918260192.53脱甲基抗螃威Pirimicarb-Uesmethyl定量离子225.1168.16019定性离子225.1180.160174.39脱甲基甲酰胺基抗场威pirimicarb-desmethyl-fbnamido定量离子253.072.04030定性离子253.0225.04015325.35克百威carbofur

19、an定量离子222165.16015定性离子222123.160322.873羟基克百威3-hydroxycarbofuran定性离子256.1175.16031定量离子23816355183313.72噬氧灵quinoxyfen定量离子3082728()43定性离子3081978048343.13乐果dimethoate定量离子2301994513定性离子23017145183518.19联苯菊酯bifen(hrin定量离子4401814039定性离子4401664051368.28氯叱嚏磺隆halosulfuron-methyl定量离子4351825044定性离子4351395056379

20、.79马拉硫磷malathion定量离子331127.16016定性离子3319960484.92马拉氧磷malaoxon定量离子315.1127.07016定性离子315.199.07031388.53嗑菌酯azoxyStrobin定量离子4043726016定性离子404344.16034392.66灭多威methomyl定量离子163883512定性离子1631063512409.31灭线磷ethoprophos定量离子243.197.06743定性离子243.1130.96726413.13三环哇Iricyclazole定量离子1901638()30定性离子1901368045427.

21、52三哇醇triadimenol定量离子296704548定性离子296994521438.91三瞠酮triadimefbn定量离子294.2197.16520定性离子294.2696535442.87杀扑磷methidathion定量离子3031455512定性离子303855532450.47水胺硫磷isocarbophos定量离子290.22313015序号保留时间中文名称英文名称离子类型QlQ3去簇电压(V)碰撞能量(eV)定性离子290.2121.13040466.08菱锈灵carboxin定量离子2361436018定性离子236876035479.40戊哇醇tebuconazol

22、定量离子308708049定性离子30815180384810.34烯畦醉diniconazol定量离子326709048定性离子32615990484912.40辛硫磷phoxim定量离子299775550定性离子2991295513508.32亚胺硫磷phosmet定量离子318160.16114定性离子31813361473.67氧亚胺硫磷phosmetoxon定量离子302.0160.07017定性离子302.0133.07()47513.67氧化萎锈灵oxycarboxin定量离子2681756021定性离子268147.160355212.84乙拌磷disulfbton定量离子27

23、5893032定性离子2756130493.25内吸磷碉demeton-S-sulfone定量离子291.0235.07()21定性离子291.0263.070162.53内吸磷-S-亚碉demeton-S-sulfbxide定量离子275.1197.07016定性离子275.1141.070297.33乙拌磷碉disulfbtonsulfone定量离子307.0153.07015定性离子307.0125.070225.39乙拌磷亚飒disulfbtonsulfoxide定量离子291.0185.06017定性离子291.0213.06012538.28异嗯哩草酮isoxaflutole定量离

24、子3602517031定性离子36022070513.86异嗯喋草酮-二酮睛Isoxaflutole-diketonitrile定量离子358.079.0-70-37定性离子358.064.0-70-685414.83乙硫磷ethion定量离子385.0199.06815定性离子385.0171.06817558.39乙霉威diethofencarb定量离子2682265512定性离子26815255325611.79乙唯硫磷etrimfbs定量离子293.1265.08023定性离子293.1125.08034576.67异丙威isoprocarb定量离子194.1955521定性离子194

25、.1137.15513583.33抑霉抑imazalil定量离子297.11598026定性离子297.12558024序号保留时间中文名称英文名称离子类型QlQ3去簇电压(V)碰撞能量(eV)5912.74荀虫威indoxacarb定量离子5281508047定性离子52824980236015.38仲丁灵butralin定量离子296.1240.14615定性离子296.1222.14631附录C(资料性)60种农药标准溶液定量离子色谱图饲料中60种农药及其代谢物的标准溶液定量离子色谱图见表C.1表C.160种农药及其代谢物的标准溶液定量离子色谱图(50gL)167151.S3!1Oe35

26、82，msw?7.o7zsTime,min图C.1阿维菌素标准溶液定量离子色谱图图C.2胺菊酯标准溶液定量离子色谱图Time,mtn图C.3毗虫咻标准溶液定量离子色谱图图C.4毗嗖醛菌酯标准溶液定量离子色谱图7410455MlJX.3E三13132图C.5丙环嗖标准溶液定量离子色谱图图C.6丙漠磷标准溶液定量离子色谱图SOMOOeOTotsVrIoTime,m图C.7虫酰肿标准溶液定量离子色谱图图C.8除虫服标准溶液定量离子色谱图SvS3e52e5OeO21421.5hw1Time,mm图C.U敌敌畏标准溶液定量离子色谱图图C.12口定虫眯标准溶液定量离子色谱图3OeS901210514771

27、2.552.051“58.M60440e4IOeS5.0e42OHOOvO140 1S f1S 153Tn, minOOeO8590”Tn.mtn图C.I3口定酰菌胺标准溶液定量离子色谱图图C.I4毒死蝉标准溶液定量离子色谱图2CWS1ssIOeS0e4OOeO-5.0Mb,-t4lJ1.241048O334032.03O图C.17多杀霉素标准溶液定量离子色谱图二苯胺标准溶液定量离子色谱图83191551.09550e4OOeO75_57a750二嗪磷标准溶液定量离子色谱图1.27IOMB838334.03NOeS01.!fl,.I1&31?017STn,man图C.20氟胺氨菊酯标准溶液定量

28、离子色谱图dj.cmc105e410511Tim.m氟甲睛标准溶液定量离子色谱图ISeSIOeS5OHOoeO12.562图C.22氟硅嗖标准溶液定量离子色谱图图C.23甲拌磷标准溶液定量离子色谱图25952051SeSIOeSSOMOOeO4c514OeO404.5SOTime,mmOeOl7T*10vU5Tim.min图C.24甲基硫菌灵标准溶液定量离子色谱图图C.25甲基异柳磷标准溶液定量离子色谱图7 9012OrSStSIOeS50e4000rV三75IoasTim.sw一一GO&5图C.26甲硫威亚碉标准溶液定量离子色谱图图C.27甲蔡威标准溶液定量离子色谱图Time, mm7.03

29、*14774.03S.O34033.O32.831O3图C28甲氟菊酯标准溶液定量离子色谱图图C.29甲霜灵标准溶液定量离子色谱图图C.30久效磷标准溶液定量离子色谱图45971.2*5185eoc4fJ6044042044.0UTn.m图C.31抗蜗威标准溶液定量离子色谱图twuZ3ES0e4OOeO图C.31脱甲基抗螃威标准溶液定量离子色谱图图C.31脱甲基甲酰胺基抗螃威标准溶液定量离子色谱图1.249%1Mt13232.030WidosTim.rmn图C.32克百威标准溶液定量离子色谱图OtOrv-ZOZS303.STim.min图C.323-羟基克百威标准溶液定量离子色谱图Se4137

30、191130342414OtO图C.33喳氧灵标准溶液定量离子色谱图图C.34乐果标准溶液定量离子色谱图103S02024022.023OM2*2.04154IOMSOtlOOeO图C.36氯毗喀磺隆标准溶液定量离子色谱图7594l105Time,min图C.37马拉氧磷标准溶液定量离子色谱图图C.37马拉硫磷标准溶液定量离子色谱图图C.39灭多威标准溶液定量离子色谱图图C.38嗒菌酯标准溶液定量离子色谱图.v图C.42三哩醉标准溶液定量离子色谱图图C.43三哩酮标准溶液定量离子色谱图Tn. mm.te304727.03162；33；4.(te33.03-2.te31.2；图C.44杀扑磷标准

31、溶液定量离子色谱图图C.45水胺硫磷标准溶液定量离子色谱图6077UeS1Q5R04e440e420*4OOeO1033612401Mbxl?f14S0e3*1l11.0OcOTime,mm图C.48喀菌酯标准溶液定量离子色谱图图C.49辛硫磷标准溶液定量离子色谱图83190.00Ii-Ir7.580Tim.图C.50亚胺硫磷标准溶液定量离子色谱图图C.50氧亚胺硫磷标准溶液定量离子色谱图744.033666128*.w2!6943e.3.032.03103OtOrr-i-103V404.5Timt.mm图C.51氧化萎锈灵标准溶液定量离子色谱图0IJa*1Z513B.5Tim.min图C.52乙拌磷标准溶液定量离子色谱图2 595 ZOeS1.55IOeS 504 OOeOt图C.52内吸磷-S-碉标准溶液定量离子色谱图图C.52内吸磷-S-亚碉标准溶液定量离子色谱图OXWO图C.52乙拌磷碉标准溶液定量离子色谱图图C.52乙拌磷亚飒标准溶液定量离子色谱图R28138602.03Z2X41.531.83IOMSOel32OOeO17.5a00103.54045Ttm.mmTimf.minTime, minZ5图C.54乙硫磷标准溶液定量离子色谱图图C.55乙霉威标准溶液定量离子色谱图工，UM图C.56乙喀硫磷标准溶液定量离子色谱图图C.57异丙威标准溶液定量离子色谱图